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This nodule is reported to be a result of electrowinning of copper, a process in which electricity is used to reduce copper oxide to copper metal, as a means of extracting the metal from its ore. It's a lot like electroplating, the only difference is that in electroplating your goal is to put copper onto something, while in electrowinning the goal is to get the copper in the first place.
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A few of the deep United States copper deposits contain some copperarsenic minerals such as enargite or tennantite. Native copper may occur in unirrportant quantities in oxidized ore deposits, but in one place in the United States (Michigan), it is a significant ore mineral associated with covellite, a copper sulfide.
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